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FaceTime over cellular: I paid full price for the iPhone 5 so that I could keep my grandfathered unlimited data plan and with my oldest now at college I like that we can hold video calls on the go. At times like this, it sure is nice to see a face and not just hear a voice.
Custom vibrations: We recently saw this cool fun way of customizing notifications when a person contacts you on the Samsung Galaxy S III. The iPhone 5 supports custom vibrations as well. Within a selected contact go down to where it states "vibration" and then tap the word, scroll down, and tap on Create New Vibration under the Custom subheading. You then simply tap out your custom vibration and save it for this contact.
Apple is good at taking what others have done before and refining it and we see the cool Windows Phone 7 swipe to reveal photo feature. Within the photo app you simply swipe to access your recently captured photos.