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The top menu choice lets you connect multiple Hotmail/Live/Outlook accounts.
The Outlook.com interface uses the familiar three-pane view.Ads appear in the right when you're not viewing content associated with a friend or contact.
Click the Chat icon (to the left of the Gear icon in the top right corner) to chat with an available contact. You can use any connected service, using the menu at the bottom of the chat pane.