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I use Skype a lot to stay in touch with friends and colleagues, and the iPad version is a solid performer. The display is used well on the tablet, and call quality is superb.
Skype- Nexus 7
Skype is a decent performer on Android, but the display is not used as well as on the iPad. Call quality varies on the Android tablet, more so than on the iPad in my experience.
This app originally appeared on the iPad, and is a great example of the way a tablet program should work. The screen use is marvelous, and performance is solid.