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2. Diplomatic car to the airport
Why the Ecuadorian embassy, of all embassies? Really, Mr. Assange, I know the Ecuadorians have been good so far -- granting him asylum and kindly putting him up in their embassy for two months -- but it's the most difficult building to escape from.
Seriously. It's nigh on impossible.
A diplomatic car remains the soil of that country even in transit, in this case Ecuador. But getting from the embassy to the car is paved with police officers ready to arrest him. Even with zip-lines and Harry Potter-like invisible cloaks, the 20-meter path between the door of the embassy to the car waiting outside is enough of U.K. soil to nab the Wikileaks founder and take him into custody.
Even if Assange did get to the diplomatic vehicle, the U.K. authorities can simply stop the car and prevent it from moving until Assange crawls out gasping for water. The U.K. can't search the car or pull Assange from the car, so sitting and waiting would be the only option.
But should he get to an airport, he would still have to check through security which remains U.K. soil, until he passes into the international zone. Diplomatic passports are to aid security, not to give the holder a right to automatic immunity.
Image credit: Google Maps.