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If I were to ever end up stranded on a desert island, I would have a near-unlimited supply of ibuprofen. There's nothing worse than being in a foreign country and either not speaking the language or know where you're going with a headache so heavy that it could kill a small elephant.
My personal trouble is that I suffer with Tourette's syndrome. Dozens of times a day, I violently twitch my head which not only strains my neck and back muscles but also often results in an excruciating headache. My cure: ibuprofen, because for some reasons paracetamol doesn't quite take the edge off.