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Outlook 2013's new Peek feature lets you quickly check your calendar by rolling a mouse over the menu bar. You can then see your appointments, and make appropriate decisions without leaving a message.
If you tap the small blue button in the Quick Access toolbar, you're switched into Office 2013's touch mode. Buttons are further apart, and icons are resized to make them easier to tap.
OneNote 2013 is designed to store your notebooks in the cloud. If you're already using SkyDrive, you're automatically connected to your existing notebooks as soon as OneNote runs for the first time.