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Under Unity, Ubuntu still makes it easy to manage your PC's settings.
Number 1: Mint
Mint 11: Based on Ubuntu 11.04, but using GNOME 2.x instead of Unity, I find Mint 11 to be the best of the Linux desktops for daily use.
Mint's GNOME interface may be old-fashioned but it still makes finding applications when you need them easy to do.