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While it is installing, pop into your Live@edu email account or your Google Apps email account and search for the relevant IMAP information.
For Google Apps users, click the Cog icon and enter Mail settings. Here, select Forwarding and POP/IMAP and make sure that the Enable IMAP option is set. From here, you can also access your Configuration settings which will be needed to set up Outlook later.
To read more on this gallery, visit the iGeneration column, where you can read more about migrating your email to Hotmail or Gmail.