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Logging back in as the Administrator, I go to the Options area as I normally would to access email settings. But as the administrator I also have other management settings such as those of the entire email organisation - this hypothetical university.
Colour key for viewers: Red border is the administrator's email view. Green border is the student user's email view. Blue border is the administrator's console.
For more background on this screenshot gallery, head over to the iGeneration blog which explains all.