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I like a good weather app, and this one is simply gorgeous on the iPad screen. It gives a simple look at the immediate forecast, and has an animated background that reflects the current weather. It's great to leave running with the iPad in the dock.
The new iPhoto app for the iPad impresses me more the longer I use it. The simple photo editing tools allow anyone to make a photo look its best with simple touch controls. It won't replace a full version of Photoshop, but many will find it sufficient for their photo editing needs.
Skype is not a new app but I find I use it a lot on the new iPad. The ability to keep in touch with family and colleagues remotely is a big boon, and the front camera of the new iPad works well with Skype.
Facetime is a nice video chat app, but most of my contacts are running Skype so that is what I use most.