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You can access the same settings as students would in Live@edu, such as POP/IMAP settings and other Exchange functionality. Users of Office 365 are also given 25GB of email storage, unlike students who are only given 5GB.
Note: to see Outlook Web App (Release 5) in action, head over to this screenshot gallery. The screenshots are exactly the same.
Connecting your email to a desktop application like Outlook 2010 is simple with Exchange connected. All folders are automatically up to date, emails are pushed through, and you can access all of the functionality that the Outlook Web App provides but from your desktop.
You can access all of the functionality that the Outlook Web App provides but from your desktop. For example, you can set automatic replies/out of office replies from your desktop. For those who use POP/IMAP do not have this functionality, however.