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Where you should be: Account settings > General tab.
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Your email can be used to find others in the same 'network' as your email domain, such as a corporate workplace or a school, college or university.
Be careful here. You can use many emails to access your Facebook profile, but these can automatically appear on your profile.
1. If you wish to disconnect from a network, you can remove your email address here, too. Simply hit Remove.
2. If you wish to remove your Facebook email, then you can do. This allows anyone outside of Facebook to contact you on the site.
Also, ensure that the box is not ticked to prevent others from downloading your email address if they decide to export their data from Facebook.