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You can customize the Start screen by adding icons that represent files or folders, including shared network drives.
If you keep your working files in a group of common locations, I recommend adding shortcuts to the Start screen so you can open those locations in Windows Explorer and switch to the Windows desktop with one quick click. See the next screen to see the icons I chose to add.
(Oh, and did you notice how different this desktop background looks from the custom background you chose for the Start screen? We'll fix that shortly.)