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I used to subscribe to and read Reader Digest religously and am enjoying it in portrait mode on the PlayBook.
Poynt is a location-based application that gives you quick access to local movies, restaurants, gas stations, and weather with search options for people and businesses.
I was a big fan of Missile Command as a kid and this game is similar with beautiful graphics. There is a bug where the banner stays on the screen too long when a round starts, but it is available for free.