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If you're ready to chat, then Windows 8's Messaging application will get you talking. It'll connect you to the chat services your Windows Account is connected to, in our case Windows Live Messenger and Facebook.
The People app in Windows 8 is just like the People Hub in Windows Phone 7, right down to the What's New view that gives you a snapshot of just what's happening in your social networks.
You can add more than just a Windows Account to the people account, linking it to address books in Exchange, Hotmail and Google, as well as to your messaging and social network contacts.