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Here's Start (and other UI hints)
When you first use a new account, animated hints appear in each of the four corners to alert you to their special functions. If you try the action and miss, you get a second level of help text and another animation.
A helpful hint for the charms menu, too
This is the animated hint that appears in the upper right corner after you sign in to a Windows 8.1 account for the first time.
The new Help + Tips app
One of the biggest criticisms of Windows 8 was its lack of any help for newcomers. The new Help _ Tips app aims to change that, with detailed information in six categories.