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To find the Windows To Go workspace creation tool, just start typing its name on the Start screen. You'll find the tool in the Settings results, right at the top of the list.
Windows 8 Enterprise comes with a simple wizard for setting up Windows To Go USB sticks. All you need is a suitable memory stick — Microsoft recommends USB 3.0 — with plenty space, and access to a suitable install image file. Start by selecting the USB drive you intend to use.
Next you'll need to select the image you want to use. IT administrators can use tools like the Microsoft Deployment Toolkit to build the appropriate WIM format files, embedding apps and customising installation options — or you can just extract the install.wim from a Windows install DVD.