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There's not much else to do when creating Windows To Go workspaces. Once you've put everything in place, just click the Create button and files and drivers will be installed on your USB stick.
It takes as long to create a Windows To Go USB device as it does to install Windows — so expect to wait fifteen minutes or so (less if you're using a device connected to a USB 3.0 port). Once the process has started there's no need for user intervention, so you can carry on with other tasks.
Once the Windows To Go installer has finished running, you'll be given the option of setting your PC to automatically boot from a USB device next time you start — something that's useful if you're going to be using Windows To Go as your default workspace. In practice, however, you're more likely to be using it with a home PC, or on the road.