SiOx memory: how it works

By | September 7, 2010, 1:05am PDT

Summary: The new memory is non-volatile, offers fast sub-100 ns switching times, can be written 10,000 times and is fully compatible with current CMOS manufacturing processes. A 1,000 bit proof-of-concept chip has been built by a private company. But those aren’t the good parts.

The recent announcement that Rice University grad student Jun Yao has demonstrated a new memory device has created a stir. As well it should.

The new device is non-volatile, offers fast sub-100 ns switching times, can be written 10,000 times and is fully compatible with current CMOS manufacturing processes. A 1,000 bit proof-of-concept chip has been built by a private company.

Those specs are better than or equal to current MLC NAND flash, but there are 3 other important advantages:

  1. Size: devices are only 5 nm wide - 1/5th the feature size of the latest flash devices - which means much higher storage capacity.
  2. Capacity: the architecture lends itself to stacking multiple dies - so-called 3D chips - to create even higher capacity devices.
  3. Simplicity: it is a 2 terminal memory, not 3 as in most memories. This reduces device size and complexity.

The device
The device uses silicon oxide (SiOx), a universal component of semiconductor devices for decades, in a novel way. The SiOx is used to create a conductor - not an insulator.

From the Rice press release:

Applying a charge to the electrodes created a conductive pathway by stripping oxygen atoms from the silicon oxide and forming a chain of nano-sized silicon crystals. Once formed, the chain can be repeatedly broken and reconnected by applying a pulse of varying voltage.

I did not find a mention of the voltage needed to form the chain, but given the feature size and mechanism I’d expect it to be much less than the 20 volts required to pump NAND flash. If correct that should also reduce the chance of catastrophic die failure when the insulation shorts out.

Here’s a graphic that starts at the chip level and goes down to the nanocrystal level:

Why the limited write/erase lifespan? Presumably the local region runs out of nearby oxygen atoms, stopping the process, accounting for the ≈10,000 write limit. Clever materials or manufacturing process engineering might increase that limit.

The Storage Bits take
It’s great to see something novel found in such a common material as SiOx. Professor James Tour, in whose lab Jun Yao works, says SiOx is one of the most studied materials on earth.

Flash designers have been sounding alarms because they aren’t sure they can go below 20nm feature sizes - a fast approaching limit. Of course, storage and semiconductor engineers have been sounding alarms for decades: that’s how you keep the suits funding research.

But this development has great promise not only for its theoretical capabilities, but because it creates technological competition. We’ll all benefit from that.

Comments welcome, of course.

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Robin Harris has been messing with computers for over 30 years and selling and marketing data storage for over 20 in companies large and small.

Disclosure

Robin Harris

Robin Harris is a president of TechnoQWAN, a consulting and analyst firm in northern Arizona. He also writes StorageMojo.com, a blog which accepts advertising from companies in the storage industry, and has a 25 year history with IT vendors. He has many industry contacts, many of whom are friends and all of whom he has opinions about. Robin has relationships with many companies in the technology industry. Every company he writes about may have sought to influence his opinion through carefully-crafted marketing messages and self-serving white papers, gifts ranging from desk calendars, t-shirts, lunches and trips as well as analyst or consulting assignments. He also invests in some technology companies. He may accept payment for services in stock as well. Robin discloses financial investments in or client relationships with companies named in Storage Bits. To help readers sort out the gold from the dross in his writings, Robin tries to communicate his reasons as clearly as he can. If you agree, you are intelligent and discerning. If you disagree, well, you disagree. In all cases, Robin encourages readers to subject everything they read, see or hear on the internet or from politicians to some simple questions: * What assumptions are implicit in the world view and judgments of the author? * What, if any, is the factual basis for the opinions the author expresses? * Is it reasonable, logical and clear? Your critical faculties: use ‘em or lose ‘em!

Biography

Robin Harris

Harris has been messing with computers for over 30 years and selling and marketing data storage for over 20 in companies large and small. He introduced a couple of multi-billion dollar storage products (DLT, the first Fibre Channel array) to market, as well as a many smaller ones. Earlier he spent 10 years marketing servers and networks. After leaving corporate life he founded TechnoQWAN, a consulting and analyst firm. He also developed StorageMojo into one of the top storage industry blogs.

Robin writes, consults, coaches and lives among the mountains of northern Arizona.

Talkback Most Recent of 15 Talkback(s)

  • RE: SiOx memory: how it works
    Sounds good..... BUT I am a little.... concerned about those 'write limits'. My one USB flash drive here at home has those write limitations (though not as low) as well so I am always looking at the blue light flashing on it thinking "Is that a read..... or a write! If it's the latter, why is it writing!?"
    ZDNet Gravatar
    Lerianis10
    7th Sep 2010
  • Write limit may not matter so much
    @Lerianis10: While a 10,000 write limit sounds bad, it's no worse than the first flash memories 20 years ago. Today the techniques for spreading the wear around and managing failures are very well-known and effective. Given that each storage element is smaller than traditional flash, at least initially you can make up for the greater wear with a lot more spare cells and probably still be competitive in price.
    ZDNet Gravatar
    zackers
    7th Sep 2010
  • RE: SiOx memory: how it works
    Yeah... the write limits are low for now, but what a great beginning. Good article, Robin. Thanks.
    ZDNet Gravatar
    ITOdeed
    7th Sep 2010
  • 20 Volts?
    I have to admit I do not know much about flash, but 20 volts sounds awfully high. Is that correct?
    ZDNet Gravatar
    Economister
    7th Sep 2010
  • ZDNet Blogger

    RE: SiOx memory: how it works
    @Economister
    Yes. That's why a fault in the insulator layer can fry the whole die pronto.

    Robin
    ZDNet Gravatar
    R Harris
    7th Sep 2010
  • Do more research. Lot's of flash show's 5V or less for reprogramming.
    @R Harris

    Look at flash datasheets. It didn't take long to find writeable flash at 1.8V(Intel & AMD), 5V (ATMEL)for ATA, 12V. I didn't find one yet that was 20V.
    ZDNet Gravatar
    MeMyselfAndI_z
    7th Sep 2010
  • RE: SiOx memory: how it works
    @Economister
    Based on the datasheets I've seen, it is high. Most of the datasheets for flash that I've found were 5V or less. And there are quite a few that are less generally around 3 Volts. See Atmel, Intel, Micronyx
    ZDNet Gravatar
    MeMyselfAndI_z
    7th Sep 2010
  • ZDNet Blogger

    RE: SiOx memory: how it works
    @MeMyselfAndI_z
    I confess to not being entirely clear on the mechanism, but the flash supply voltages don't tell the whole story. The voltage is pumped up to ?20 volts for a write.

    Several large users of flash chips have confirmed that shorts in flash insulation layers will fry the entire chip. That is why the higher quality flash drives use a form of RAID to protect data against total loss.

    Robin
    ZDNet Gravatar
    R Harris
    7th Sep 2010
  • Sounds like an excellent EPROM replacement...
    ...I suspect that the trade off, 1/5th the space, would negate any power concerns. Besides, that is a 20v pulse of extremely short duration and an undefined (By this article) amperage. The full article from Jun Yao can be obtained at http://www.ruf.rice.edu/~mobile/publications/yao09small.pdf
    ZDNet Gravatar
    ReadWryt (error)
    7th Sep 2010
  • ZDNet Blogger

    RE: SiOx memory: how it works
    @readwryt@...
    Thanks for the link! I looked for the paper and couldn't find it - and I know most of the tricks.

    Robin

    Update: I had not trouble getting the paper from your link - I just couldn't find it before finishing the post. Again, thanks!
    ZDNet Gravatar
    R Harris
    7th Sep 2010
  • RE: SiOx memory: how it works
    @R Harris
    Try right click -> save as
    ZDNet Gravatar
    fgendel
    7th Sep 2010
  • Oooof!
    @R Harris I linked straight to the PDF of the paper. You can right click and copy the URL and save it to your desktop, then open it with Acrobat Reader if you don't have the Acrobat plugin for your browser...Sorry about that.
    ZDNet Gravatar
    ReadWryt (error)
    7th Sep 2010
  • RE: SiOx memory: how it works
    The correct online paper link is as follows:
    http://pubs.acs.org/doi/abs/10.1021/nl102255r

    The link you provided is an old one before finding the mechanism.
    ZDNet Gravatar
    yugi321
    7th Sep 2010
  • RE: SiOx memory
    Stanford Ovshinsky put a great deal of time and effort (and money) into something that looked very similar. So far (unlike some of his other ventures) this hasn't been a great success.
    Maybe shrinking geometries and nano-tubes will provide the final piece of the jigsaw. Maybe
    ZDNet Gravatar
    shtromer
    7th Sep 2010
  • Is this true crossbar addressing?
    From what I can glean from this article and the paper, it looks at though each bit cell can be addressed separately, rather than in big blocks such as conventional flash. If so, does this eliminate all the huge write issues of traditional flash that make writes take so long?

    Also, I note from the Wikipedia article on resistive switching, apparently SiO2 resistive switching has been studied since 1967 ( https://secure.wikimedia.org/wikipedia/en/wiki/Resistive_random-access_memory#cite_note-7 )

    Also, is this a form of the memristor? These are currently based on titanium dioxide, but at least superficially have much in common with the SiOx approach discussed here.
    ZDNet Gravatar
    zackers
    7th Sep 2010

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