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Office 365 includes self-service tools so users can work with their own mail accounts, seeing just how much space they have left, and how to connect other mail clients to their accounts.
Log on as a user, and you'll see a basic start page that gives quick access to web mail and SharePoint team sites, as well as download links for applications. You'll also find help in setting up a desktop PC to work with the Office 365 service.
If you've used Outlook Web Apps with on-premises Exchange, then you'll find the online OWA that's part of Office 365 very familiar.